Tertiary Butyl Hydroperoxide (TBHP) [MC-RM-AC-010]

Tertiary Butyl Hydroperoxide (TBHP) [MC-RM-AC-010]

Product Description

Tertiary Butyl Hydroperoxide (TBHP) is an organic peroxide with the chemical formula (CH₃)₃COOH, commonly used as an oxidizing agent in chemical reactions. It is widely applied in chemical synthesis, polymerization reactions, and industrial production, particularly in organic chemistry, polymer manufacturing, and pharmaceuticals. Below is a detailed explanation of Tertiary Butyl Hydroperoxide (TBHP):

Basic Information:
  • Chemical Formula: (CH₃)₃COOH
  • Molecular Weight: 166.2 g/mol
  • Appearance: A colorless liquid with a smell similar to alcohol, usually found in concentrations of 70% or 90% in aqueous solution or pure liquid form.
  • Solubility: TBHP is highly soluble in water and miscible with many organic solvents.
Chemical Properties:
  • Strong Oxidizing Agent: TBHP is a potent oxidizing agent capable of providing oxygen in various reactions. It can break down molecular structures and initiate oxidation reactions, such as epoxidation of alkenes and peroxidation of aromatic hydrocarbons.
  • Instability: As a peroxide, TBHP is highly reactive and can decompose, releasing oxygen and tertiary butyl radicals ((CH₃)₃C·). It must be handled carefully to avoid explosive decomposition.
  • Decomposes Easily: TBHP can decompose when exposed to light, heat, or reducing agents, leading to the release of hydrogen peroxide (H₂O₂) and free radicals.
Safety and Precautions:
  • Corrosive and Irritating: TBHP is highly irritating and corrosive to the skin, eyes, and respiratory system. Direct contact may cause burns or irritation. Proper protective equipment, such as gloves, goggles, and protective clothing, should be worn when handling TBHP.
  • Storage Conditions: TBHP should be stored in a cool, dry place away from heat and light. Due to its peroxide nature, it should be kept away from reducing agents and unstable conditions to prevent decomposition or explosions.
  • Decomposition: TBHP decomposes easily when exposed to high temperatures or certain chemicals. It should be used in a controlled environment to avoid.
Main Applications:
  1. Organic Synthesis as an Oxidizing Agent:
    • TBHP is widely used in organic chemical reactions as an oxidizing agent. For example, it is employed in the epoxidation of alkenes, converting alkenes into epoxides.
    • It is also used in the peroxidation of aromatic hydrocarbons, where it serves as an oxidizing agent to initiate the formation of peroxides.
  2. Polymerization Reactions:
    • Polymerization Initiator: TBHP is used as a free radical initiator in the polymerization of various plastics, such as polyethylene, polypropylene, and polyvinyl chloride (PVC). It generates free radicals that promote the polymerization of monomers.
    • In copolymerization reactions, TBHP effectively initiates the reaction, leading to the polymerization of co-monomers.
  3. Pharmaceutical Industry:
    • TBHP is used in some pharmaceutical syntheses as an oxidizing agent or initiator in reactions to create specific chemical structures.
    • It is particularly useful in the synthesis of anticancer drugs and other complex organic molecules where oxidation is required.
  4. Cleaning and Disinfection:
    • As a strong oxidizing agent, TBHP is used in some disinfection processes, particularly for water treatment and surface disinfection, to remove microorganisms and sanitize surfaces.
  5. Laboratory Applications:
    • In laboratories, TBHP is commonly used in organic synthesis, analytical chemistry, free radical reactions, and other analytical experiments. It is also used in gas analysis and various other testing methods.

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